Synthesis, structure, and magnetic properties of a new eight-connected metal-organic framework (MOF) based on Co4 clusters

A hydrothermal reaction of cobalt nitrate, 4,4'-oxybis(benzoic acid) (OBA), 1,2,4-triazole, and NaOH gave rise to a deep purple colored compound [Co(4)(triazolate)(2)(OBA)(3)], I, possessing Co(4) clusters. The Co(4) clusters are connected together through the tirazolate moieties forming a two-dimensional layer that closely resembles the TiS(2) layer. The layers are pillared by the OBA units forming the three-dimensional structure. To the best of our knowledge, this is the first observation of a pillared TiS(2) layer in a metal-organic framework compound. Magnetic studies in the temperature range 1.8-300 K indicate strong antiferromagetic interactions for Co(4) clusters. The structure as well as the magnetic behavior of the present compound has been compared with the previously reported related compound [Co(2)(μ(3)-OH)(μ(2)-H(2)O)(pyrazine)(OBA)(OBAH)] prepared using pyrazine as the linker between the Co(4) clusters.     

Production and payment policies for an imperfect manufacturing system with discount cash flows analysis in fuzzy random environments

ABSTRACT

This paper considers an imperfect manufacturing system with credit policies in fuzzy random environments. The supplier simultaneously offers the retailer either a permissible delay in payments or a cash discount and retailer in turn provides its customer a permissible delay period. We used an alternate approach – discount cash flow analysis to establish an inventory problem. It is assumed that the elapsed time until the machine shifts from ‘in-control’ state to ‘out-of-control’ state is characterized as a fuzzy random variable. As a function of this parameter, the profit function is also a random fuzzy variable. Based on the credibility measure of fuzzy event, the model with fuzzy random elapsed time can be transformed into a crisp model . We establish several theoretical results to obtain the solution that provides the largest present value of all future cash flows. Finally, numerical example is given to illustrate the results and obtain some managerial insights.     

Properties of the He ground state from He neutron knockout

The unbound nucleus ⁷He, produced in neutron-knockout reactions with a 240 MeV/u ⁸He beam in a liquid-hydrogen target, has been studied in an experiment at the ALADIN-LAND setup at GSI. From an R-matrix analysis the resonance parameters for ⁷He as well as the spectroscopic factor for the ⁶He(0⁺) + n configuration in its ground-state have been obtained. The spectroscopic factor is 0.61 confirming that ⁷He is not a pure single-particle state. An analysis of ⁵He data from neutron-knockout reactions of ⁶He in a carbon target reveals the presence of an s  -wave component at low energies in the α+n$\alpha +\mathrm{n}$ relative energy spectrum.     

A three-dimensional metal-organic framework with a distorted Kagome related layer showing canted antiferromagnetic behaviour

Three-dimensional [Mn(3){C(6)H(3)(COO)(3)}(2)] comprising two-dimensional -Mn-O-Mn- distorted Kagome layers, formed by two geometrically different hexa-coordinated Mn(2+) ions, show less frustration and spin canted long range ordering possibly due to antisymmetric exchange.     

Synthesis, structure and optical properties of rare-earth benzene carboxylates

Two series of rare-earth isophthalates of the general formula, [M(2)(H(2)O)][{C(6)H(4)(COO)(2)}(2){C(6)H(4)(COOH)(COO)}(2)].H(2)O, M=La (I), Pr (Ia), and Nd (Ib) and [M(2)(H(2)O)(2)][{C(6)H(4)(COO)(2)}(3)].H(2)O, M=Y (II), Gd (IIa), and Dy (IIb) have been prepared by the reaction of the corresponding trivalent lanthanide salts and isophthalic acid under mild hydrothermal conditions. The La (I), Pr (Ia) and Nd (Ib) have MO(9) polyhedra connected to the isophthalate anions forming a two-dimensional structure, whereas Y (II), Gd (IIa) and Dy (IIb) have MO(7) and MO(8) polyhedral units connected to the isophthalate anions forming a different, but related two-dimensional structure. Both the structures are stabilized by hydrogen bonding and pi...pi/CH...pi interactions. Partial substitution of Eu and Tb (2 and 4%) at the La (I) and Y (II) sites give rise to characteristic red/pink or green luminescence, indicating a ligand-sensitized metal-centered emission. The Nd (Ib) compound shows interesting UV and blue emission through an up-conversion process.     

Role of temperature and time in the formation of infinite -M-O-M- linkages and isolated clusters in MOFs: a few illustrative examples

The role of temperature and time of reaction in the formation of metal-organic frameworks (MOFs) has been studied in two systems of compounds, manganese oxybis(benzoate) and manganese trimellitates, and the results compared and contrasted with other similar studies in the literature. The investigation reveals the formation of six different phases in oxybis(benzoate) and three phases in trimellitate systems. The low-temperature phases in both systems of compounds possess Mn 4 cluster units linked by the carboxylate ligands, while the high-temperature phase, irrespective of the duration of the reaction, has a three-dimensional structure with -Mn-O-Mn- linkages with brucite-related layers pillared by oxybis(benzoate) and Kagome-related layers pillared by trimellitate ligands. In all of the preparation, the reactions appear to have thermodynamic control as a function of the temperature. The isolation of low-dimensional structures in manganese oxybis(benzoate) at moderate time and temperature indicates possible kinetic control. The formation of reactive low-dimensional phases has been rationalized by considering the local charge distribution around the Mn site and also invoking a possible dissolution-recrystalization mechanism.     

Tuning of texture and surface chemistry of carbon xerogels

The influence of different activation processes on the textural and surface chemical properties of carbon xerogels was studied. Carbon xerogels were prepared by the conventional sol-gel approach using resorcinol and formaldehyde; two different pHs of sol-gel processing led to carbon materials with distinct pore size distributions. The materials were subjected to controlled activation by three different methods: activation by oxygen plasma, activation by HNO(3), and activation by diluted air. Treatments with HNO(3) and diluted air created oxygen groups on the external surface as well as inside the pore channels, whereas plasma is more suitable for introducing oxygen groups selectively on the external surface. Nevertheless, it was shown that samples with wider pores can be oxidized to some extent on the pore interiors by plasma. Significant changes in total surface area by air activation were observed.     

Activation of Aromatic C−F Bonds by a N-Heterocyclic Olefin (NHO)

A N-heterocyclic olefin (NHO), a terminal alkene selectively activates aromatic C−F bonds without the need of any additional catalyst. As a result, a straightforward methodology was developed for the formation of different fluoroaryl-substituted alkenes in which the central carbon–carbon double bond is in a twisted geometry.     

Energy spectra and angular distribution of projectile-like fragments in 84 MeV <Superscript>12</Superscript>C + <Superscript>169</Superscript>Tm

Kinetic-energy spectra and angular distribution of projectile-like fragments have been measured in the reaction of 84 MeV ¹²C on ¹⁶⁹Tm, using the surface barrier silicon-based ΔE-E telescopes. The fragments close to the projectile show typical spectra of quasi-elastic transfer reactions, which were found to be in agreement with the calculations based on the direct surface transfer reaction model. A significant cross-section of fast alpha-particles was found at forward angles, reminiscent of incomplete fusion reactions, which could be explained in terms of the direct surface transfer reaction model after taking into account the level density of continuum states in the heavy reaction product. The results have been explained in terms of the continuous evolution of the reaction mechanism as a function of the mass transfer. Received: 13 March 2002 / Accepted: 3 May 2002